崔香枝，研究员 

　　介孔与低维纳米材料课题组 

　　021-52412708 

　　cuixz@mail.sic.ac.cn 

　　  

　　教育经历：  

　　1999—2003，郑州大学，材料科学与工程，学士学位  

　　2003—2006，郑州大学，无机非金属材料，硕士学位  

　　2006—2009，中国科学院上海硅酸盐研究所，材料物理化学，博士学位 

　　工作经历：  

　　2009—至今，中国科学院上海硅酸盐研究所，高性能陶瓷和超微结构国家重点实验室，助理研究员、副研究员、研究员  

　　2013—2014，美国科罗拉多矿业大学，访问学者 

　　  

　　曾获得奖励、荣誉称号： 

　　　入选为中国科学院青年创新促进会会员（2012）  

　　　中科院 上海硅酸盐研究所所“优秀个人”（2011）  

　　　中科院“优秀博士学位论文、院长奖获得者科研启动专项资金”的资助（2010）  

　　　中科院 “百篇优秀博士论文”（2010）  

　　　上海市研究生优秀成果奖（2010）  

　　　中科院“院长奖学金”优秀奖（2009） 

　　  

　　科研工作简介： 

　　针对基于氢能的清洁能源—聚合物膜燃料电池（质子交换膜燃料电池和甲醇燃料电池）在应用中存在的卡脖子问题，开展了电解水制氢（HER）、甲醇电催化氧化（MOR）、氢气电催化氧化（HOR）、氧气电催化还原（ORR）等相关高效、低成本电催化材料的研制，研究材料组成与电催化性能间的构效关系，阐明相应的电催化机制。 

　　在Energy Environ. Sci、ACS Catal.、J. Mater. Chem. A 、Chem. Sci.等期刊发表论文70余篇，H因子25。 

　　  

　　科研成果： 

　　1.表面电化学重构与电催化性能调控  通过电化学方法将纳米材料的表面进行原位重构，得到富高电催化活性位点的表面，从而显著提高材料的HER电催化活性。相关工作发表在J. Mater. Chem. A，Chem. Sci., Science China Materials等期刊上。   

 

J. Mater. Chem. A, 2019, 7, 6285–6293

Chem. Sci., 2019, 10, 2019–2024   

　　2.构建非Pt的过渡金属氧化物基质子交换膜燃料电池阳极电催化剂材料，获得高效的阳极氢电氧化（HOR）催化性能，以及高效的甲醇催化氧化（MOR）性能。相关工作发表在Energy Environ. Sci.，ChemSusChem, Electrochimica Acta等期刊上。 

ChemSusChem 2014, 7, 135 -145 

Energy Environ. Sci., 2015, 8, 1261-1266 　  

　　3.过渡金属和N共掺碳（M-N-C）的设计及ORR电催化动力学机制探讨，探讨了M-N-C材料在酸、碱性介质中的活性位点，阐明ORR反应的动力学控速步骤。 相关工作发表在J. Catal, Carbon, Electrochimica Acta等期刊上。   

Journal of Catalysis 2016, 344, 455-464

Journal of Catalysis 2017, 356, 229-236

Journal of Catalysis 2019, 372, 174-181 　　  

　　4.复合物催化剂材料中的协同催化机制 探讨多组分复合催化剂中不同功能组分在多步反应过程中的催化机制。相关工作发表在ACS Catal., ChemCatChem等期刊上。 

ACS Catal., 2014, 4 , 2195-2206 

　　  

　　科研成果（近5年代表性论文）： 

1. Han Tian, Xiangzhi Cui*, Liming Zeng, Liang Su, Yiling Song, Jianlin Shi*.  Oxygen vacancy-assisted hydrogen evolution reaction of the Pt/WO₃ electrocatalyst, J. Mater. Chem. A, 2019, 7, 6285-6293.  
2. Liang Su, Xiangzhi Cui*, Ting He, Liming Zeng, Han Tian, Yiling Song, Kai Qi, Bao Yu Xia*, Surface reconstruction of cobalt phosphide nanosheets by electrochemical activation for enhanced hydrogen evolution in alkaline solution, Chem. Sci., 2019, 10, 2019-2024.  
3. Yiling Song, Xiaohua Zhang, Xiangzhi Cui*, Jianlin Shi*. The ORR kinetics of ZIF-derived Fe-N-C electrocatalysts, J Catal., 2019, 372, 174-181.  
4. Xiangzhi Cui*, Lu Meng, Xiaohua Zhang, Xingang Wang, Jianlin Shi. Heterogeneous atoms-doped titanium carbide as a precious metal free electrocatalyst for oxygen reduction reaction, Electrochimica Acta 2019, 295, 384-392.  
5. Liming Zeng, Xiangzhi Cui*, Jianlin Shi*. A facile strategy for ultra small Pt NPs being partially embedded in N-doped carbon nanosheet structure for efficient electrocatalysis. Sci China Mater 2018, 61(12): 1557-1566.  
6. Xiaohua Zhang, Ping Lu, Chen Zhang, Xiangzhi Cui*, Yingfeng Xu, Haiyun Qu, Jianlin Shi*. Towards understanding ORR activity and electron-transfer pathway of M-Nx/C electro-catalyst in acidic media, J. Catal., 2017, 356: 229-236.  
7. Liming Zeng, Xiangzhi Cui*, Lisong Chen, Ting Ye, Weimin Huang, Ruguang Ma, Xiaohua Zhang, Jianlin Shi*, Non-noble bimetallic alloy encased in nitrogen-doped nanotubes as ahighly active and durable electrocatalyst for oxygen reduction reaction, Carbon, 2017, 114: 347-355.  
8.  Xiangzhi Cui, Zile Hua, Lisong Chen, Xiaohua Zhang, Hangrong Chen, Jianlin Shi*. Manganese Oxide Nanorod-Decorated Mesoporous ZSM-5 Composite as a Precious-Metal-Free Electrode Catalyst for Oxygen Reduction, ChemSusChem, 2016, 9(9): 1010-1019.  
9. Xiaohua Zhang, Ping Lu, Xiangzhi Cui*, Lisong Chen, Chen Zhang, Mengli Li, Yingfeng Xu, Jianlin Shi*. Probing the electro-catalytic ORR activity of cobalt-incorporated nitrogen-doped CNTs, J. Catal., 2016. 344:455-464.
10. Xiangzhi Cui, Jianlin Shi*, Sn-based catalysts for Baeyer-Villiger oxidations by using hydrogen peroxide as oxidant, Sci China Mater, 2016, 59(8): 675-700. 
11. Xiangzhi Cui, Yan Zhu, Zile Hua, Jingwei Feng, Ziwei Liu, Lisong Chen, Jianlin Shi*, SnO₂ nanocrystal-decorated mesoporous ZSM-5 as a precious metal-free electrode catalyst for methanol oxidation. Energy Environ. Sci., 2015, 8(4), 1261-1266. 
12. Xiangzhi Cui, Lisong Chen, Yongxia Wang, Hangrong Chen, Wenru Zhao, Yongsheng Li, Jianlin Shi*, Fabrication of hierarchically porous RuO₂-CuO/Al-ZrO₂ composite as highly efficient catalyst for ammonia-selective catalytic oxidation. ACS Catal., 2014, 4(7), 2195-2206 
13. Xiangzhi Cui, Yongxia Wang, Lisong Chen, Jianlin Shi*, Synergetic catalytic effects in tri-component mesostructured Ru–Cu–Ce oxide nanocomposite in CO oxidation. ChemCatChem, 2014, 6(10), 2860-2871.  
14. Xiangzhi Cui, Jianlin Shi*, Yongxia Wang, Yu Chen, Lingxia Zhang, Zile Hua, Mesostructured platinum-free anode and carbon-free cathode catalysts for durable proton exchange membrane fuel cells. ChemSusChem, 2014, 7(1), 135-145.