包山虎    研究员

　　工业陶瓷研究中心组

　　工作电话: 021-6990 6203,Fax 021-6990 6223

　　电子邮件: shanhu.bao@mail.sic.ac.cn 

 

教育经历：

1980-1982  内蒙古师范大学化学专业

1982-1985  北京师范大学化学系 化学专业 学士

1991-1992  武汉大学化学系 分析化学助教进修班

1997-2003  日本信州大学大学院 工学系研究科 获得硕士，博士学位

 

工作经历：

1985-1997  内蒙古师范大学化学系任教，讲师

2003-2004  东京工业大学大学院，生命理工学研究科，博士后

2004-2009  日本产业技术综合研究所，中部中心，特别研究员

2009-2010  日本纪本电子工业株式会社，研究员

 

岗位任职经历

2010—至今，中国科学院上海硅酸盐研究所，高性能陶瓷和超微结构国家重点实验室，研究员

 

曾获得奖励、荣誉称号：

科研工作简介：

1）开展新型镁合金调光镜薄膜材料的基础与理论研究，根据调光原理及劣化机制研究的基础上提出缓冲膜和保护膜的技术，使得调光镜的开关寿命有了很大的提高。如下图所示，镁合金调光镜是在氢气气氛中变成透明薄膜，空气或氧气中又回到金属态的可逆循环的，全发射性的新型节能薄膜材料。高分子或者无机氧化物保护层可以起到延长薄膜可逆循环的寿命，又有增透作用。

Mg合金薄膜气致变色原理

氢化过程： Mg₂Ni + 2H₂ <=> Mg₂NiH₄(茶色)

Mg + H₂ <=> MgH₂（无色）

脱氢过程： Mg₂NiH₄ + O₂ <=>  Mg₂Ni + 2H₂O

2MgH₂ + O₂ <=>  2Mg + 2H₂O  

2) 电致变色器件是在电场的作用下，通过导入电荷（离子或电子）从低透过率的着色状态到高透过率的消色状态之间产生的可逆变化的现象，在外观上表现为颜色态及透明态之间的可逆变化。主要有电致变色智能窗，储存器，显示器，汽车防眩后视镜，电子束印刷及传感器，及隐身伪装技术等领域的应用研究。WO₃基全固体电致变色智能窗及汽车防眩镜性能，下图为ITO/WO₃/Ta₂O₅/NiO_x/ITO全固体电致变色智能透明态与着色态的照片。研究解决反射型及透过型全固体电致变色器件的产业化关键技术。

 

3)氧化钒材料在68°C相变附近发生可逆的半导体-金属相变特性，伴随相变发生其光，电，磁等性能也巨大的可逆性变化，而被广泛关注。VO₂基温控智能窗的服役性能研究方面，通过多层膜的光学设计，温控智能氧化钒薄膜的可见光透过率提高至60%，循环寿命达到3.5万次以上。

4）红外阻隔功能氧化物薄膜的制备与性能研究。如下图提示。掺杂或无掺杂的氧化钨薄膜具有很好的紫外及红外阻隔功能，且可见光区透过率高，达到70%，在节能玻璃及红外隐身材料方面具有潜在的应用潜力。

 

科研成果：

2017年

1. La Mao，Ning Li，Saren，Shanhu Bao*，Ping Jin, Excellent photochromic properties of an oxygen-containing yttrium hydride coated with tungsten oxide (YHx:O/WO3), Scripta Materialia, 14 (2018), 36-40

2. La Mao，Huaijuan Zhou，Ning Li，Yunchuan Xin，Saren，Shanhu Bao*，Ping Jin，Improved performance of Mg-Y alloy thin film switchable mirrors after coating with a superhydrophobic surface，Appl. Surf. Sci., 403（2017），23-28

2016年

1. Pd–MgNix nanospheres/black-TiO2 porous films with highly efficient hydrogen production by near-complete suppression of surface recombination, Jianyun Zheng, Shanhu Bao, Xiaoli Zhang , Haibo Wu , Rongxiang Chen Ping Jin, Applied Catalysis B: Environmental 2016, 183, 69-74 

2. Jingting Zhu，Aibin Huang，Haibin Ma，Yunxiang Chen，Sanpei Zhang，Shidong Ji， Shanhu Bao^*，Ping Jin，Hybrid Film of VO₂ Nanoparticles and Nickel(II)-based Ligand Exchange Thermochromic System: Excellent Optical Performance with A Temperature Responsive Colour Change，New Journal of Chemistry，2016.12.26

3. Yi, Na，Bao, Shanhu，Zhou, Huaijuan，Xin, Yunchuan，Huang, Aibin，Ma, Yining，Li, Rong，Jin, Ping，Preparation of microstructure-controllable superhydrophobic polytetrafluoroethylene porous thin film by vacuum thermal-evaporation，Frontiers of Materials Science，2016.9.01，10(3)：320-327

4. Achieving high-performance planar perovskite solar cells with co-sputtered Co-doping NiO x hole transport layers by efficient extraction and enhanced mobility A. B. Huang, J. T. Zhu, J. Y. Zheng, c Y. Yu,  Y. Liu, S. W. Yang,  S. H. Bao, L. Lei and P. Jin J., Mater. Chem. C 2016, 4, 10839-10846 

5. Thermochromic multilayer fi lms of WO3/VO2/WO3 sandwich structure with enhanced luminous transmittance and durability Shiwei Long , Huaijuan Zhou, Shanhu Bao, Yunchuan Xin, Xun Cao and Ping Jin, RSC Adv 2016, 6, 106435-106442 

6. Synthesis of fl ake-like VO2 (M) by annealing a novel (NH4)0.6V2O5 phase and its thermochromic characterization Yining Ma , Huaijuan Zhou , Jingting Zhu , Shidong Ji , Shanhu Bao , Rong Li Ping Jin, Ceramics International 2016, 42, 16382-16386 

7. Use of ZnO as antireflective, protective, antibacterial, and biocompatible multifunction nanolayer of thermochromic VO2 nanofilm for intelligent windows Huaijuan Zhou  , Jinhua Li  , Shanhu Bao, Jian Li, Xuanyong Liu, Ping Jin, Applied Surface Science 2016, 363, 532-542 

8. Optical and electrical switching properties of VO2 thin film on MgF2 (111) substrate Huaijuan Zhou, Jinhua Li, Yunchuan Xin, Guangyao Sun, Shanhu Bao, Ping Jin, Ceramics International 2016, 42, 7655-7663 

2015年 

1. Electron transfer induced thermochromism in a VO2–graphene–Ge heterostructure. Huaijuan Zh ou, Jinhua Li, Yunchuan Xin, Xun Cao, Shanhu Bao and Ping Jin, J. Mater. Chem. C , 2015,3, 5089 

2. The potential cytotoxicity and mechanism of VO2 thin films for intelligent thermochromic windows, Huaijuan Zhou Jinhua Li, Shanhu Bao, Donghui Wang, Xuanyong Liu and Ping Jin, RSC Adv., 2015, 5, 106315 

3. TiO2(R)/VO2(M)/TiO2(A) multilayer film as smart window: Combination of energy-saving, antifogging and self-cleaning functions Jianyun Zheng, Shanhu Bao, Ping Jin, Nano Energy (2015) 11 , 136–145 

4. Optical and electrical properties of thermochromic VO2 thin films on Pt layers H. J. Zhou1, J. H. Li, X. Cao, S. H. Bao1 and P. Jin，Materials Research Innovations，Volume 19, Supplement 4, 2015，S246-S250 

5. The optical properties of low infrared transmittance WO3-x nanocrystal thin films prepared by DC ,Yunc huan Xin, Huaijuan Zhou,Xiaojie Ni, Ying Pan, Xiaoli Zhang, JianYun Zheng, Shanhu Bao^* and Ping Jin, RSC Adv., 2015, 5, 57757 

6. Optical switching properties of Pd-Ni thin film top-capped switchable mirrors, Xiao- Li ZHANG, Shan-Hu BAO^* , Yun-Chuan XIN, Xun CAO, and Ping JIN, Front. Mater. Sci. 2015, 9(3): 227–233 

7. Optical properties and switching durability of TiO2 top-coated magnesium–nickel thin film switchable, Shanhu Bao^*, Xiaoli Zhang, Ping Jin, and Kazuki Yoshimura, Japanese Journal of Applied Physics 54, 045501 (2015) 

2014年 

1. Huaijuan Zhou, Xun Cao, Meng Jiang, Shanhu Bao, and Ping Jin, Surface plasmon resonance tunability in VO2/Au/VO2 thermochromic structure, Laser & Photonics Reviews, 8,No. 4, 617–625 (2014), 

2. Meng Jiang,Yamei Li,Shaotang Li,Huaijuan Zhou,Xun Cao,Shanhu Bao,Yanfeng Gao,Hongjie Luo,and Ping Jin, Room Temperature Optical Constants and Band Gap Evolution of Phase Pure M1-VO2Thin Films Deposited at Different Oxygen Partial Pressures by Reactive Magnetron Sputtering, Journal of Nanomaterials, Volume 2014, Article ID 18395, 

3. Meng Jianga,Xun Cao, Shanhu Bao,HuaijuanZhou,PingJin, Regulation of the phase transition temperature of VO2thinfilms deposited by reactive magnetron sputtering without doping, Thin Solid Films, 562 (2014) 314–318, 

4. Meng Jiang, Shanhu Bao, Xun Cao, Yamei Li, Shaotang Li，Huaijuan Zhou, Hongjie Luo, Ping Jin, Improved luminous transmittance and diminished yellow color in VO2 energy efficient smart thinfilms by Zn doping, Ceramics International, 40 (2014) 6331–6334, 

5. Y. Guo, S. Bao*, J. Zhengand P. Jin, High sensitivity detection of hydrogen/deuterium based on palladium top capped magnesium alloy thin films, Materials Research Innovations, 2014 VOL18, 

6. Jian-Yun Zheng,Shan-Hu Bao,Yu Guo,and Ping Jin*, Anatase TiO2 Films with Dominant {001} Facets Fabricated by DirectCurrent Reactive Magnetron Sputtering at Room Temperature:Oxygen Defects and Enhanced Visible-Light Photocatalytic Behaviors, Appl. Mater. Interfaces, 2014, 6, 5940-5946, 

7. Jian-Yun Zheng,Shan-Hu Bao,Yu Guo,and Ping Jin*, Natural Hydrophobicity and Reversible Wettability Conversion of Flat Anatase TiO2Thin Film, Appl. Mater. Interfaces, 2014, 6, 1351-1355, 

8. Jian-Yun Zheng,Shan-Hu Bao,Yu Guo,and Ping Jin*, Ti O2films prepared by DC reactive magnetron sputtering at room temperature: Phase control and photocatalytic properties, Surface & Coatings Technology, 240 (2014) 293–300, 

9. Jian-Yun Zheng,Shan-Hu Bao,Yan-Hong Lv  and Ping Jin*,Activation and Enhancement of Room-Temperature Ferromagnetism in Cu-Doped Anatase TiO2 Films by Bound Magnetic Polaron and Oxygen Defects, Appl. Mater. Interfaces, 2014, 6, 22243-22249, 

2012年

1. Shanhu Bao, Yasusei Yamada, Kazuki Tajima, Ping Jin, Masahisa Okada, and Kazuki Yoshimura, Switchable mirror based on Mg–Zr–H thin films, J. Alloys Comp., 513 (2012) 495– 498

 

详细介绍：http://www.sic.cas.cn/kybm/kybm8/ry/201709/t20170920_4862796.html